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Lithium Niobate (LiNbO3) Crystal EO/PO Components Telecom Defense High-Frequency SAW
Introduce
Lithium niobate (LN) is a ferroelectric material with excellent electro-optic, nonlinear, and piezoelectric properties.
Specification
Material | Optical Grade LiNbO3 wafes | |
Curie Temp | 1142±2.0℃ | |
Cutting Angle | X/Y/Z etc | |
Diameter/size | 2"/3"/4"/6"/8" | |
Tol(±) | <0.20 mm | |
Thickness | 0.1 ~ 0.5mm or more | |
Primary Flat | 16mm/22mm /32mm | |
TTV | <3µm | |
Bow | -30<bow<30 | |
Warp | <40µm | |
Orientation Flat | All available | |
Surface Type | Single Side Polished /Double Sides Polished | |
Polished side Ra | <0.5nm | |
S/D | 20/10 | |
Edge Criteria | R=0.2mm or Bullnose | |
Optical doped | Fe/Zn/MgO etc for optical grade LN< wafers | |
Wafer Surface Criteria | Refractive index | No=2.2878/Ne=2.2033 @632nm wavelength |
Contamination, | None | |
Particles ¢>0.3 µ m | <= 30 | |
Scratch , Chipping | None | |
Defect | No edge cracks, scratches, saw marks, stains | |
Packaging | Qty/Wafer box | 25pcs per box |
Properties
Thermal Properties
From a thermal perspective, lithium niobate (LiNbO₃) crystals exhibit excellent stability. They possess a high Curie temperature (~1142°C), meaning they retain piezoelectric properties even at elevated temperatures. This thermal stability ensures reliable functionality under high-temperature conditions, enhancing their practicality in high-temperature applications.
Mechanical Properties
Mechanically, lithium niobate is relatively hard and durable. The crystal has a Mohs hardness of approximately 5, comparable to glass or tooth enamel. This characteristic enhances its resistance to physical stress, making it ideal for applications requiring mechanical robustness.
Acousto-Optic Properties
Lithium niobate crystals demonstrate remarkable acousto-optic properties, characterized by high acousto-optic coefficients. These crystals can effectively couple acoustic and optical waves, enabling light modulation via sound. This property is widely exploited in acousto-optic devices.
Ferroelectric Properties
LiNbO₃ is a ferroelectric crystal, meaning it exhibits spontaneously polarized domains that can be reoriented by an external electric field. This feature is utilized in memory devices, electro-optic modulators, and other applications requiring precise control of polarization.
Physical Properties
A critical attribute of lithium niobate crystals is their significant optical nonlinearity, which underpins their broad utility in optics. The crystals also display birefringence, splitting incident light into two orthogonally polarized beams.
Chemical Properties
LiNbO₃ demonstrates outstanding chemical stability, making it highly attractive for diverse applications. It exhibits strong resistance to water and other chemicals, enabling use in environments where chemical resistance is essential.
Electrical Properties
As a piezoelectric material, lithium niobate uniquely converts mechanical stress into electrical charge. This property is leveraged in devices such as sensors and transducers.
Optical Properties
Lithium niobate crystals possess excellent optical properties, including high transmission across the visible to mid-infrared spectral range. This broad transmission window plays a pivotal role in optical applications, enabling efficient light propagation and interaction.
Applications of Lithium Niobate (LiNbO₃)
Piezoelectric Applications
Lithium niobate crystals exhibit outstanding piezoelectric performance due to their high Curie temperature,
low temperature coefficient of piezoelectricity, high electromechanical coupling coefficient, low dielectric loss, stable physicochemical properties, excellent machinability, and capability to fabricate large-sized, high-quality crystals. Compared to conventional piezoelectric materials like quartz, lithium niobate features higher acoustic velocity, enabling the development of high-frequency devices.
These properties make lithium niobate suitable for resonators, transducers, delay lines, filters, and other components. Applications span civilian fields such as mobile communications, satellite communications, digital signal processing, televisions, broadcasting, radar, and remote sensing, as well as military sectors including electronic countermeasures, fuzes, and guidance systems.
Optical Applications
Beyond its piezoelectric properties, lithium niobate (LiNbO₃) crystals exhibit rich photoelectric effects, with electro-optic effects and nonlinear optical effects being particularly prominent and widely utilized. Additionally, LiNbO₃ crystals can be fabricated into high-quality optical waveguides via proton exchange or titanium diffusion, and periodically poled crystals through poling reversal. These capabilities enable their applications in electro-optic modulators, phase modulators, integrated optical switches, electro-optic Q-switches, electro-optic deflectors, high-voltage sensors, wavefront sensing, optical parametric oscillators, and ferroelectric superlattices. Furthermore, LiNbO₃-based components such as birefringent wedge prisms, holographic optical devices, infrared pyroelectric detectors, and erbium-doped waveguide lasers have also been reported.
Q1: What is lithium niobate (LiNbO₃)? What are its core properties?
A1:
Lithium niobate (LiNbO₃) is a ferroelectric material with key properties:
Electro-optic effect: Enables light control for high-speed optical modulators.
Nonlinear optics: Supports frequency conversion (e.g., second-harmonic generation).
Piezoelectric effect: Converts mechanical stress to electrical signals for sensors.
High Curie temperature (~1142°C): Stable under extreme conditions.
Broad optical transparency: Effective from 400 nm (visible) to 5 µm (mid-infrared).
Q2: What are the main applications of lithium niobate?
A2:
Key applications include:
Optical communications: Modulators, wavelength division multiplexers.
Nonlinear optics: Lasers (OPO, SHG), optical parametric oscillation.
Piezoelectric devices: SAW filters, ultrasonic transducers.
Electro-optic devices: Q-switches, photonic switches.
Defense & aerospace: Radar, electronic countermeasures, radiation detectors.
Q3: What is lithium niobate?
A13:
Lithium niobate (LiNbO₃) is a ferroelectric material with electro-optic, piezoelectric, and nonlinear optical properties. It is widely used in optical communications, sensors, and laser devices.
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